As more attention is focused toward carbon dioxide emissions into the environment, conversion of CO2 to useful chemicals can utilize the extra carbon dioxide captured from power plant stack gas, instead of sequestration. The mainstream method of...
This thesis describes 1) the kinetics of vapor phase place exchange reactions on films of gold monolayer protected clusters (Au MPCs) to alter the functionality of the Au MPCs, 2) applications of the reaction for altering chemiresistive sensing...
Our research activities are based on the catalytic systems that provide resource-saving synthetic methodologies through gold-catalyzed reactions of alkynes and alkenes. We have worked on three applications: i) an effective and straightforward...
4-hydroxy-2-nonenal (4-HNE) and propene-2-al (acrolein) are highly reactive á,â-unsaturated aldehydes. 4-HNE and acrolein are generated in vivo as products of lipid peroxidation. These aldehydes are implicated in the onset of several diseases...
The current study examined how Disclosure, Stereotype Disconfirming Information, and Stereotype Disconfirming Information and Disclosure Combined) influences an individual's stigma (stereotype endorsement, emotional reactions, and discrimination)...
This study focuses on how the 2001 consolidation of the Louisville Division of Police (LPD) and Jefferson County Police Department (JCPD) impacted police officers' perception of fairness of the process. To accomplish this, the study asked four...
The oxidation of metallothiolates is complicated by "non-innocence" or potential
redox activity of sulfur to yield thiyl (RS•) radicals. In some instances, the one-electron
oxidation of metal thiolates yields a product with the unpaired...
Human arylamine N-acetyltransferase (NAT) is a phase II cytosolic enzyme that occurs as two isozymes, NAT1 and NAT2. This family of polymorphic enzymes catalyzes the detoxification and/or activation of many aromatic and heterocyclic amine drugs and...
Molybdenum-sulfur complexes have developed a lot of interest in the chemistry of metal-coordinated sulfur due to their importance in biological systems and in industrial processes like catalysis. For example, in biological processes molybdenum has...
Down syndrome--Patients; Williams syndrome--Patients; Social interaction in children; Social perception in children
The present project examined the regulatory function of social referencing in two neurodevelopmental disorders that have been well defined genetically and are characterized by differing patterns of socio-cognitive development: Down syndrome (DS)...
High solids processing of biomass slurries provides the following benefits: maximized product concentration in the fermentable sugar stream, reduced water usage, and reduced reactor size. However, high solids processing poses mixing and heat...
This dissertation deals with various imidazole compounds with emphasis on hydrogen bond interactions and weaker intermolecular forces. New amide functionalized polyimidazole metal binding pockets are able to form intramolecular six-membered...
Achievement motivation in children; Personality and motivation; Motivation (Psychology); Poor children--Psychology
The current study was designed to better understand the early behavioral and emotional factors influencing young children's responses to challenge, which have important implications for learning. Understanding why children respond to challenge as...
In this thesis self-assembled growth of Ag2Ga nano-needles on batch fabricated
micro-grippers are reported. The room temperature growth of Ag2Ga nano-needles have
been recently developed as stylus for Atomic Force Microscopy (AFM). Integration...
Freer, Charles Lang, 1856-1919; Freer Gallery of Art
This qualifying paper examines the contradiction of a public museum dedicated to one man's vision of art collecting. Charles Lang Freer established the Freer Gallery of Art in 1906, regarded as the first national public art museum on the National...
Over the last 15 years, researchers have explored the use of piezoresistive microcantilevers/resonators as gas sensors because of their relative ease in fabrication, low production cost, and their ability to detect changes in mass or surface stress...
This thesis and exhibition examine the connection between neurobiology and Op Art. Neurobiological explanations of Op Art's effects are explored as a means to offer insight into the processes of the human mind and eye, and to provide explanations...
Background The anthracycline doxorubicin (DOX) is widely used as an effective antineoplastic drug. Cardiotoxicity leading to congestive heart failure is the primary factor limiting the clinical use of DOX. However, although a variety of approaches...
Green River Valley (Ky.)--History--19th century; Green River Valley (Ky.)--Economic conditions--19th century; Farms, Small--Kentucky--History
This study focuses on the expansion of the Green River's economic and political importance within Kentucky and how it impacted small farmers of the region. It challenges the idea that small farmers played an insignificant role in the agriculture...
Barbershops--Social aspects; African American men--Social life and customs; African American men--Conduct of life; African American men--Psychology
Labeled as a man's environment, the Black barbershop is a sacred location for
Black men. Yet, it is unclear how Black men communicate in the Black barbershop.
This research study examined the communicative process of Black men within the...
