This thesis reports the reactivity of the trithiolato Ru complex PPN[Ru(DPPBT)3] (DPPBT = 2-diphenylphosphinobenzenethiolate) (1a) with alkenes upon oxidation. Complex 1a in acetonitrile shows two redox events at -345 mV and +455 mV in the square...
Introduction: Autism is a complex developmental disability that typically appears during
the first three years of life, and is the result of a neurological disorder that affects the
normal functioning of the brain, impacting development in the...
DNA microarrays--Statistical methods; Gene expression--Statistical methods
Data derived from gene expression microarrays are frequently used to identify candidate genes which can characterize and distinguish between two biological phenotypes. A key step in this process is the selection of an appropriate test statistic to...
The oxidation of metallothiolates is complicated by "non-innocence" or potential
redox activity of sulfur to yield thiyl (RS•) radicals. In some instances, the one-electron
oxidation of metal thiolates yields a product with the unpaired...
This thesis is based on work done as part of a bigger project supported by Naval Research Laboratories (NRL). A MOSIS fabricated micro hotplate is simulated using the CAD software CoventorWare. There are three different sized hotplates in one die;...
Sensor networks are just in their infancy. Their use will continue to grow as the technology becomes cheaper and more efficient. A current shortcoming with sensor networks is the inability to efficiently provide secure communications. As sensor...
The field of bone densitometry has grown rapidly, particularly in the past 15 years. Many techniques are now available from which the physician may choose. The focus of this research is on Dual-Energy X-Ray Absorptiometry (DXA) and Quantitative...
Stores & shops; Plumbing stores; Buildings; Utility poles
Address: 1534 Bardstown Road, Louisville, Kentucky. The Laib Co., a plumbing fixtures store on Bardstown Road, is a brick and stone building featuring a suspended sign with a clock above the entryway. Homes can be seen behind the store to the...
College graduates--Relocation; Educational attainment; Migration, Internal--United States
As state policymakers draw clearer connections between the college-level attainment of their residents and the corresponding economic and social benefits, there is great need for more data and information regarding the production and migration of...
African American men--Mental health; Depression in men; Depression, Mental--Social aspects
Background: In any given year depression affects as many as 121 million people worldwide and 20 percent or 19 million people in the U.S. suffer from at least one episode of depression during their lifetime. In the U.S., depression has a substantial...
Medical appointments and schedules--Data processing; Medical appointments and schedules--Mathematical models; Scheduling--Computer programs; Medical offices--Data processing
In order to allow quality healthcare to be available to more people, healthcare must be as affordable as possible. Ideally this will be done through the elimination of the waste that is built into the current healthcare system. One area that is...
Juvenile delinquents--Rehabilitation; Juvenile delinquents--Mental health services; Juvenile delinquents--Psychology; Juvenile delinquents--Substance use
Juvenile delinquency with co-occurring substance abuse and mental health disorders has become an increasing problem within the United States. In part this can be attributed to the excessive number of delinquent youth entering the juvenile justice...
Autistic children--Rehabilitation; Social skills in children; Autistic children--Behavior modification; Group work in education; Peer-group tutoring of students
Social reciprocity deficits are a core feature of the autism spectrum disorders (ASD) and a major source of impairment regardless of cognitive or language ability (Carter, Davis, Klin, & Volkmar, 2005). Since these impairments do not naturally...
Many conflicting reports have been given in the literature concerning the effect of various factors on the rate of reversal of figure and ground in reversible perspective.
Flugel (7, 8) suggested that changes in eye movement increased the number of...
Vicinal dithioethers and alkenyl thioethers were synthesized under environmentally
friendly conditions using alkyne and thiol in water. Alkynes were also used to develop a
multibond-fonning reaction that fonned cyclic ketones or ketoesters through...
Parents of children with disabilities; Grief; People with mental disabilities--Family relationships
This dissertation is an investigation into the intensity, nature, predictors, and time
course of grief that parents of adult children with a severe mental illness experience. This
is an area of research that has not been fully understood or...
Hemolysis, the major cause for specimen rejection in clinical laboratories is defined as the rupture of red blood cell membranes, resulting in the release of hemoglobin into the plasma. Blood flow in needles causes hemolysis resulting in...
Ground-level ozone forecast models were developed for the following middle and small metropolitan areas in Kentucky: Ashland, Bowling Green, Owensboro, and Paducah. These models were nonlinear regression models, based on models previously developed...
Since the beginning of the VLSI era, various technologies have been adopted for developing the design and characterization of analog circuits. For robust design, the influences of the process parameter variations have been considered over the...
