This thesis reports the reactivity of the trithiolato Ru complex PPN[Ru(DPPBT)3] (DPPBT = 2-diphenylphosphinobenzenethiolate) (1a) with alkenes upon oxidation. Complex 1a in acetonitrile shows two redox events at -345 mV and +455 mV in the square...
This dissertation is an examination of fire department response times in eight major cities of the United States including Houston, TX, Charlotte, NC, St. Paul, MN, Portland, OR, Seattle, WA, Louisville, KY, San Francisco, CA and Miami, FL. This...
Simplified modeling generates a great deal of interest in the area of crashworthiness analysis. Modeling methods used to create simplified computer models for crashworthiness have been well developed. In advanced simplified models, researchers...
Clustered longitudinal data is often collected as repeated measurements on subjects over time arising in the clusters. Examples include longitudinal community intervention studies, or family studies with repeated measures on each member. Meanwhile,...
Computational grids are some of the largest computer systems in existence today. Unfortunately they are also, in many cases, the least reliable. This research examines the use of redundancy with permutation as a method of improving reliability in...
The role of the active site tyrosine residue in the Co-C5' bond activation in the
context of adenosylcobalamin-dependent mutases has been computationally
investigated. The density functional, complete active space self-consistent field
and quantum...
The oxidation of metallothiolates is complicated by "non-innocence" or potential
redox activity of sulfur to yield thiyl (RS•) radicals. In some instances, the one-electron
oxidation of metal thiolates yields a product with the unpaired...
Heart--Diseases--Patients--Rehabilitation; Data mining
The purpose of this paper is to examine the process of text mining and using the results to show the possible benefits of cardiopulmonary rehabilitation. The 555 patients enrolled in the study were receiving inpatient cardiopulmonary...
This thesis reports the reactivity of the rhenium-thiolate complex, tris(2-diphenylphosphinobenzenethiolato)rhenium(III), [Re(DPPBT) 3 ] ( 1 ) and its oxidized derivatives with ethylene. The reactivity has been studied by electrochemical,...
The purpose of this study was to examine common algebra-related misconceptions and errors of middle school students. In recent years, success in Algebra I is often considered the mathematics gateway to graduation from high school and success...
Nuclear magnetic resonance spectroscopy; Spectrum analysis--Data processing
Since its development, nuclear magnetic resonance (NMR) has become one of the primary methods of chemists for structure elucidation, which is the determination of a compound's molecular structure. Current software packages enable scientists to...
An investigation was made into the relative costs of excavation retention by two systems: conventional soldier pile-wale-tieback support, and support by soil nailing. The investigation included design of excavation supports by the two...
This thesis is a social and military history of the First Battalion of the 27th Foot, the Inniskilling Regiment, at the Battle of Waterloo. Crucial to success in battle is the cohesion of units and their ability to withstand punishment and keep...
This thesis looks at the optimization of fluid flow and mass transfer using computational fluid dynamics (CFD) in a micro fluidic coulter counter. CFD will be used to solve equations of fluid flow and mass transfer to see how molecules within the...
The purpose of this research study is to examine the use of time series forecasting and text mining to investigate the prescription of antibiotics. The specific objective is to examine the relationship between the total payments, private insurance...
Istanbul (Turkey)--Buildings, structures, etc.; Architecture, Ottoman--Turkey--Istanbul--History
Following the conquest of Constantinople in 1453 by the Ottomans, a new trend in architecture developed that achieved a balance between the traditional Ottoman building practices of Bursa and Edirne with the styles found in Byzantium and the West....
Prints--Kentucky--Louisville--Exhibitions; Painting--Kentucky--Louisville--Exhibitions; Art quilts; Block designs; Screen process printing; Feminism and art
This thesis explores pattern juxtaposition using traditional American quilt block designs as the compositional basis for nine works pieced from screen printed paper. In the 1970s, the quilt was celebrated for its apparent connection to Modernist...
Acetone--Analysis; Air quality monitoring stations
Zinc oxide (ZnO) based gas sensors with sliver ion exchanged ZSM-5 (Ag+ZSM-5) zeolite overlayer were created and tested for detection of acetone vapor in air. The ZnO and Ag+ZSM-5 films were deposisted on 400µm by 400µm platinum interdigitated...
Child molesters; Child sexual abuse--Research; Child sexual abuse--Diagnosis
An exploratory cross national study was conducted to determine if factors identified in the existing literature predictive for CSA in developed countries were also valid and predictive CSA factors for females in Belize, a developing country. The...
Many conflicting reports have been given in the literature concerning the effect of various factors on the rate of reversal of figure and ground in reversible perspective.
Flugel (7, 8) suggested that changes in eye movement increased the number of...
