This thesis describes 1) the kinetics of vapor phase place exchange reactions on films of gold monolayer protected clusters (Au MPCs) to alter the functionality of the Au MPCs, 2) applications of the reaction for altering chemiresistive sensing...
The research in this dissertation describes a simple electrochemical approach for fabricating nanoscale (metal/metal) or molecular (metal/polymer or self assembled monolayer (SAM)/metal) junctions. The fabrication involves metal deposition on one...
This thesis reports the reactivity of the trithiolato Ru complex PPN[Ru(DPPBT)3] (DPPBT = 2-diphenylphosphinobenzenethiolate) (1a) with alkenes upon oxidation. Complex 1a in acetonitrile shows two redox events at -345 mV and +455 mV in the square...
The role of the active site tyrosine residue in the Co-C5' bond activation in the
context of adenosylcobalamin-dependent mutases has been computationally
investigated. The density functional, complete active space self-consistent field
and quantum...
Children with visual disabilities--Services for--Kentucky; Children with visual disabilities--Education--Kentucky; Self-help devices for people with disabilities--Kentucky; Students with disabilities--Services for--Kentucky
Assistive technology (AT) helps make the curriculum accessible to students with visual impairments. Studies have shown that half of these students are using assistive technologies. The purpose of this study was to seek a better understanding of the...
Intelligent transportation systems; Air quality; Air--Pollution
Environmental or air quality impacts of Intelligent Transportation Systems (ITS)
are very difficult to measure. Some researchers have attempted to quantify the effects of
individual ITS application on emissions; yet, the effects of ITS as a whole...
This thesis reports the reactivity of the rhenium-thiolate complex, tris(2-diphenylphosphinobenzenethiolato)rhenium(III), [Re(DPPBT) 3 ] ( 1 ) and its oxidized derivatives with ethylene. The reactivity has been studied by electrochemical,...
The oxidation of metallothiolates is complicated by "non-innocence" or potential
redox activity of sulfur to yield thiyl (RS•) radicals. In some instances, the one-electron
oxidation of metal thiolates yields a product with the unpaired...
Optical properties of carbon nanotubes have recently attracted considerable amount of attention. Due to there direct band gap material characteristic these and dimension of the order of nano meters they find potential applications in the field of...
Understanding of the band structure of the new nano materials is essential to have a deeper insight into their optical and electrical properties. Along with the existing techniques used for characterization of nano-materials, it is also important...
This study explores four economic development theories – classical location theory, human capital theory, agglomeration economies theory and creative cities theory, and their effectiveness in explaining the spatial distribution of high tech...
Internet in education; Universities and colleges--Faculty--Attitudes; Education, Higher--Computer network resources; Education, Higher--Effect of technological innovations on
This study examined faculty levels of implementation of Web-based instructional technology (WBIT) and computer self-efficacy beliefs (CSE) as factors associated to faculty perception of institutional mechanisms and its relative importance as...
Health--Information resources; Health--Information services; Information networks
Background: Failure to achieve their goals of over 200 U.S. Health Information Exchange Networks (HIENs) which formed or operated in the U.S. from 2004 to 2010, lost time, capital and opportunity at individual, organizational and societal levels,...
The discovery of carbon nanotubes and subsequently graphene has led to an interest in carbon materials as sensing elements due to their unique properties. Graphene is a 2-dimensional material that has a large surface area that can be exposed to...
III-nitrides (InN, GaN, AlN) are some of the most promising materials for making blue light emitting diodes (LED), blue laser diodes (LD) and high power, high temperature field effect transistors (FET). Current techniques produce GaN films with...
The Adoption and Safe Families Act created specific outcomes for permanency for children in foster care. The purpose of these outcomes is to decrease the number of children in long term foster care. Seven years have passed since ASFA was signed...
The application of carbon nanotubes (CNTs) has captivated the curiosity of today's experts due to the escalating potential in the field of electronic detection of biomolecules. Their extreme environmental sensitivity and small size make them ideal...
Nitrile hydratase (NHase) is a metalloenzyme that contains a non-heme iron (III)
or non-corin cobalt (III) in a non-redox active role. NHase is used as biocatalyst in the
industry for the hydrolysis of nitriles to arnides. The trivalent metal ions...
Remote terminal units (RTUs) are perimeter supervisory control and data acquisition (SCADA) devices that measure and control actual physical devices. Cyber security was largely ignored in SCADA for many years, and the cyber security issues that now...
