Archaeologists use soil analysis to detect chemicals, like phosphate, to indicate areas of anthropogenic activity. Phosphate detection is a multi-step process, which makes standard techniques time consuming. Kinetic studies decreased the analysis...
Residential buildings account for a large portion of total energy consumption in the United States. Residential energy usage can be dramatically reduced by improving the efficiency of building envelope systems. One such method is to incorporate...
The role of the active site tyrosine residue in the Co-C5' bond activation in the
context of adenosylcobalamin-dependent mutases has been computationally
investigated. The density functional, complete active space self-consistent field
and quantum...
Understanding of the band structure of the new nano materials is essential to have a deeper insight into their optical and electrical properties. Along with the existing techniques used for characterization of nano-materials, it is also important...
This thesis reports the reactivity of the rhenium-thiolate complex, tris(2-diphenylphosphinobenzenethiolato)rhenium(III), [Re(DPPBT) 3 ] ( 1 ) and its oxidized derivatives with ethylene. The reactivity has been studied by electrochemical,...
This study compared brief, single sessions of physical activity (PA, self-paced treadmill walking) and relaxation/meditation (R/M, the "Body Scan") on positive and negative affect and anxiety measures in female undergraduates. Both were...
Several technical and economic obstacles currently hamper the industrial development of ethanol from biomass. One of the key bottlenecks is the slow kinetics of the enzymatic hydrolysis of cellulose, and the subsequent rate reduction as the...
A novel catalyst with hydro-desulfurization and hydrogenation capabilities was tested with the aim of producing ultra-low sulfur and aromatics diesel oil. The catalytically active phase is nickel in a reduced valence state on a carrier made of zinc...
4-hydroxy-2-nonenal (4-HNE) and propene-2-al (acrolein) are highly reactive á,â-unsaturated aldehydes. 4-HNE and acrolein are generated in vivo as products of lipid peroxidation. These aldehydes are implicated in the onset of several diseases...
The Technical Advisory Group (TAG) of the Innovative Treatment Remediation Demonstration Program (ITRD) made technology recommendations after reviewing thirty in situ remediation technologies for implementation at the Paducah Gaseous Diffusion...
A potential source of fine grained suspended sediments in a stream system is the
upper hillslopes of the drainage. Quantifying the sediment produced and transported to a
stream from these hillslopes is challenging because of the complex nature of...
This dissertation describes (1) size-dependent electrochemical oxidation/stripping of gold and silver nanoparticles (NPs), (2) alloying of copper with gold nanoparticles at underpotential deposition potentials, (3) electrochemical characterization...
Preventive maintenance is a broad term that encompasses a set of activities aimed at improving the overall reliability and availability of a system. Preventive maintenance involves a basic trade-off between the costs of conducting...
This dissertation describes galvanic exchange of silver (Ag) nanostructures with PdCl42- in 1) various PdCl42- concentrations, 2) the presence of 0.1 M cetyitrimethylammonium bromide (CTAB), and 3) the presence of 0.1 M potassium bromide (KBr). It...
Ten algal isolates were obtained from soil into axenic culture and placed into defined media containing from 0 to 50 ppm of DDT, 2, 4-D,2,4,5-T, rotenone, or malathion (in two purities, 95 and 99%). For nine of the isolates, growth was measured...
The management of power and the optimization of systems generating and using power are critical technologies. A new architecture is developed to advance the current state of the art by providing an intelligent and autonomous solution for power...
A projected high penetration of battery electric vehicles (BEV s) in the market will introduce an additional load in the electricity grid. Furthermore, uncontrolled BEV charging from residential users will exacerbate the existing peak load during...
This study examined two questions related to interpersonal change as an outcome of Time-Limited Interpersonal Therapy (TLIPT). The first asked if clients experience both symptom change and interpersonal change when treated with TLIPT. The second...
The area of Knowledge discovery and data mining is growing rapidly. Feature Discretization is a crucial issue in Knowledge Discovery in Databases (KDD), or Data Mining because most data sets used in real world applications have features with...
